Manganese brown is a mixed oxide of manganese and was only seldom employed in oil painting. The name has been used also for other pigments such as umber.
Timeline for brown pigments - ColourLex
5 Famous Paint Colors First Made From Mummies, Insects, and Ancient Rocks
Discover the Richness of Manganese Brown in Art
inorganic artificial - ColourLex - Art and Science
Discover the Richness of Manganese Brown in Art
Old pigments painting blog: Vandyke Brown
Pigments - ColourLex
Umber - ColourLex
inorganic artificial - ColourLex - Art and Science
5 Famous Paint Colors First Made From Mummies, Insects, and Ancient Rocks
Manganese brown - ColourLex
Pigments - ColourLex
burnt umber – Cultural Heritage Science Open Source