Answer (1 of 5): The earliest soaps were made using ashes of wood or other plants, which contains potash (potassium carbonate). You can also use potassium hydroxide. These will produce a softer soap, and in the case of KOH, liquid soap. Those are pretty much your only practical choices. Alkaline
How to Make Soap (With or Without Lye)
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What are some natural substitutes to using lye in a soap recipe
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Can we really make soap without NaOH? This product says like that
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Are there any alternatives to sodium hydroxide (lye) in making
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